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Spray Away Slab Cleaner

MSDS Spray Away Slab Cleaner

Material Safety Data Sheet

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Spray Away Slab Cleaner

The Hitt Companies, Inc.

Santa Ana, CA 92704

EMERGENCY PHONE: 1-800-969-6699 or (714) 979-1405 (24 hours)

Issue Date: 06/11/2009

Bulk cleaner used primarily to remove adhesives and adhesive residue.

Specific Use: citrus base industrial cleaner

SECTION 2: INGREDIENTS

Ingredient                                                                                                       C.A.S. No.                         % by Wt    

D-LIMONENE                                                                                                   5989-27-5                          40 - 50

PROPYLENE GLYCOL TERT-BUTYLETHER                                                          57018-52-7                        40 - 50

TRIPROPYLENE GLYCOL ETHER                                                                        20324-33-8                         5 - 10          

NONYLPHENOL GLYCOL ETHER                                                                        26027-38-3                         5 - 10

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Odor, Color, Grade: transparent, citrus odor

General Physical Form: Liquid

Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and

explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Combustible liquid and

vapor. May cause severe eye irritation. May cause allergic skin reaction. May cause target organ effects.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.

Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause:

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

May be absorbed through skin and cause target organ effects.

Inhalation:Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting, May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air.

If Swallowed:Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature                  No Data Available

Flash Point                                             112.00 ºF

Flammable Limits – LEL                     No Data Available

Flammable Limits – UEL                     No Data Available

5.2 EXTINGUISHING MEDIA

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures:

containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained

breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards:

travel long distances along the ground or floor to an ignition source and flash back. Combustible liquid and vapor.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition

information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to

local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING

Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this  product. Wash exposed areas thoroughly with soap and water. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid contact with oxidizing agents. Keep out of the reach of children.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

Use with appropriate local exhaust ventilation.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact with vapors, mists, or spray.

The following eye protection(s) are recommended: Safety Glasses with side shields.

8.2.2 Skin Protection

Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber, Polyvinyl Alcohol (PVA).

8.2.3 Respiratory Protection

Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half face piece or full face air-purifying respirator with organic vapor cartridges.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

8.3 EXPOSURE GUIDELINES

None Established

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade:                                                         Transparent, citrus odor

General Physical Form:                                                     Liquid

Autoignition temperature                                                 No Data Available

Flash Point                                                                       112.00 ºF

Flammable Limits – LEL                                                    No Data Available

Flammable Limits – UEL                                                    No Data Available

Boiling point                                                                     340.00 ºF

Vapor Density                                                                  >=1.00 [Ref Std: AIR=1]

Vapor Pressure                                                                1.6000 mmHg [Details: CONDITIONS: @ 68F]

Specific Gravity                                                                 Not Applicable

pH                                                                                    0.860 [Ref Std: WATER=1]

Melting point                                                                    No Data Available

Solubility in Water                                                            Moderate

Evaporation rate                                                              No Data Available

Volatile Organic Compounds                                            775.00 g/l

Percent volatile                                                                85 - 95 % weight

VOC Less H2O & Exempt Solvents                                   Approximately 775 g/l [Test Method: calculated SCAQMD rule 443.1]

Viscosity                                                                          <=100.0 centipoise

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: Strong oxidizing agents

Hazardous Polymerization: Hazardous polymerization will not occur

Hazardous Decomposition or By-Products

Substance                               Condition

Carbon monoxide                   During Combustion

Carbon dioxide                        During Combustion

SECTION 11: Not determined.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product

in a permitted hazardous waste facility.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

SECTION 14:TRANSPORT INFORMATION

ID Number(s):

62-4456-6530-0, 62-4456-7530-9, 62-4456-8530-8, 62-4456-9530-7

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard – No    Immediate Hazard - Yes Delayed Hazard - No

SECTION 16: OTHER INFORMATION

NFPA Hazard Classification

Health: 2 Flammability: 2

Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.